(Dimethylphosphoryl)methanaminium chloride
نویسندگان
چکیده
The crystal structure of the title salt, C(3)H(11)NOP(+)·Cl(-), is primarily built from centrosymmetric dimers of two cations, connected head-to-tail by two charge-supported strong N-H⋯O hydrogen bonds, with a graph-set descriptor R(2) (2)(10). The chloride counter-anions connect these dimeric cationic units into chains along the a-axis direction.
منابع مشابه
trans-Dichloridotetrakis[(dimethylphosphoryl)methanaminium-κO]cobalt(II) tetrachloridocobaltate(II)
The asymmetric unit of the title structure, [CoCl2(C3H11NOP)4][CoCl4]2, consists of one half of the trans-dichlorido-tetra-kis-[(di-methyl-phosphor-yl)methanaminium]cobalt(II) tetra-cation lying on an inversion center and one tetra-chloridocobaltate(II) dianion on a general position. Four O-coordinated cationic (di-methyl-phosphor-yl)methanaminium (dpmaH(+)) ligands occupy the equatorial coordi...
متن کاملPseudosymmetric fac-diaquatrichlorido[(dimethylphosphoryl)methanaminium-κO]manganese(II)
In the title compound, [Mn(C3H11NOP)Cl3(H2O)2], the Mn(II) metal center has a distorted o-cta-hedral geometry, coordinated by the three chloride ligands showing a facial arrangement. Two water mol-ecules and the O-coordinated dpmaH cation [dpmaH = (di-methyl-phosphor-yl)methanaminium] complete the coordination sphere. Each complex mol-ecule is connected to its neighbours by O-H⋯Cl and N-H⋯Cl hy...
متن کامل(4-Methoxyphenyl)methanaminium chloride
In the crystal structure of the title salt, C(8)H(12)NO(+)·Cl(-), the methoxy group of the cation is co-planar with the phenylene moiety with an r.m.s. deviation from the mean plane of only 0.005 Å. The ammonium N atom deviates from this plane by 1.403 (1) Å. In the crystal, the (4-meth-oxy-phen-yl)methan-aminium cations and chloride anions are linked by N-H⋯Cl and C-H⋯O hydrogen bonds, resulti...
متن کاملComplexation Reaction Using Ammonium Based Chloride Compounds for Preparation of Eutectic Mixtures
In this study, we are interested in the eutectic processing of chloride compounds and decided to focus on ammonium based compounds that can provide sufficient insight in the fundamental chemistry. 10 types of ammonium based chloride compounds namely ammonium chloride, methanaminium chloride, dimethylammonium chloride, trimethylammonium chloride, tetramethylammonium chloride, dodecyltrimethylamm...
متن کامل(4-Chlorophenyl)methanaminium chloride hemihydrate
In the title hydrated salt, C(7)H(9)ClN(+)·Cl(-)·0.5H(2)O, the water O atom lies on a crystallographic twofold axis. In the crystal, the monoprotonated 4-chloro-benzyl-ammonium cation forms N-H⋯Cl and N-H⋯O hydrogen bonds and the water mol-ecule forms O-H⋯Cl hydrogen bonds, generating layers lying parallel to the bc plane.
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره 68 شماره
صفحات -
تاریخ انتشار 2012